Group 13 Element Trihalide Complexes of Anionic N‐Heterocyclic Carbenes
نویسندگان
چکیده
منابع مشابه
Advances in the development of complexes that contain a group 13 element chalcogen multiple bond.
Inorganic group 13 element (M) chalcogenides (E) based on the general formular M2E3 are ubiquitous in synthesis, catalysis and material science. The parent ME fragment which aggregates to form three dimensional networks in the condensed phase can be expected to exhibit multiple bond character between the elements. Low temperature matrix isolation techniques are required to investigate the natur...
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Group-13 metal acetylacetonates [M(acac)3] (M = Al, Ga, In) or Al(OiPr)3 react with a complex [Pd(catphosH)2] that may act as chelating ligand towards a second metal, or with a mixture of catechol phosphine (catphosH2) and [PdCl2(cod)], to give heterometallic complexes featuring either dinuclear M(catphos)2Pd or trinuclear M{(catphos)2Pd}2 motifs. Characterisation of the products by crystallogr...
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A sterically demanding iminophosphonamine ligand [(2,6-iPr2C6H3N)P(Ph2)(NtBu)]H (LH) and its lithium derivative [(2,6-iPr2C6H3N)P(Ph2)(NtBu)](Li·2THF) (1) were used to prepare complexes of group 13 elements. The reaction of LH with AlH3·NMe2Et and AlMe3 respectively, affords [LAlH2]2 (2) and LAlMe2 (3). The lithium derivative 1 when treated with the MCl3 compound of group 13 yields [(2,6-iPr2C6...
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ژورنال
عنوان ژورنال: Chemistry – An Asian Journal
سال: 2020
ISSN: 1861-4728,1861-471X
DOI: 10.1002/asia.201901774